低发射率兼低光泽颜填料Al-Sr10的制备及其消光机理研究

Preparation of Low Emissivity and Low Gloss Filler Al-Sr10 and its Extinction Mechanism

  • 摘要: 为了探究Al-Sr10具有低光泽属性的本质,对该材料进行X射线衍射、X射线能量色散谱、面扫元素分析、8~14 μm红外发射率、光泽度及400~760 nm可见光反射率测试。并采用高能球磨法制备该颜填料,通过扫描电子显微镜等手段探究Al-Sr10颜填料的组分、形态和光学性能随球磨时间的变化。结果表明,Al-Sr10表面易氧化形成灰黑色氧化锶,以及固溶体中的锶元素产生等离激元效应共同作用导致材料消光;Al-Sr10颜填料的物相不会随球磨时间变化,在一定时间内,材料的片状化程度、发射率和光泽度性能随时间的延长得到改善,其中球磨15 h后的颜填料其片状化程度高,发射率低至0.123,光泽度低至3.8。

     

    Abstract: To evaluate the nature of the low gloss properties of Al-Sr10, X-ray diffraction, X-ray energy dispersive spectroscopy, face scan elemental analysis, 8−14 μm infrared emissivity, gloss, and 400−760 nm visible reflectance tests are performed on the material. The Al-Sr10 filler is prepared by high-energy ball milling, and changes in the components, morphology, and optical properties of the Al-Sr10 filler with the ball milling time are evaluated by scanning electron microscopy. The results show that the surface of Al-Sr10 is easily oxidized to form gray-black strontium oxide, and the effect of strontium in the solid solution leads to the extinction of the material. The components of the Al-Sr10 filler do not change with the ball milling time, and the lamellarization, emissivity, and gloss properties of the material increase with time. The degree of lamellarization of the filler after 15 h of ball milling is high, the emissivity is as low as 0.123, and the gloss is as low as 3.8.

     

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